At a recent shale gas symposium in South Africa a question was asked “if hydraulic fracturing is so safe, why do drilling operators working in Pennsylvania’s Marcellus Shale Play dispose the backflow out of state in Ohio.” The question was satirically proposed by a rather uninformed anti-fracking environmentalist. His point was to show that even a natural gas producing state wants nothing to do with the disposal of the hydraulic fluid’s flowback (chemical-laced wastewater).
This discussion addresses the attendees question from a chemical perceptive. It is not intended as a review of the relationship between wastewater injection wells and earthquakes. Let it suffice to say that injection well seismicity typically ranges from 1 to 4 on the Richter scale and rarely cause damage. Nevertheless, the industry is minimizing the risk of seismicity by: assessing susceptibility when identifying or permitting injection sites; requiring seismic monitoring at active well sites; limiting well pressure thresholds by decreasing the amount of water pumped into wells and reducing the pressure at which it is pumped; and recycling and reusing wastewater.
Hydraulic fracturing is the process used to stimulate gas production from conventional oil and gas reservoirs. The process requires between 3 to 5 million gallons of fluid per well. The fracturing fluid is a proprietary mixture consisting of at least 98% water and sand with the remaining 2%, or less, of chemical additives, each having a specific function.
Although there are dozens to hundreds of chemicals, which could be used as additives, typically, there are no more than 12 chemicals used in the fracturing process. Most of the additives are commonly used household or personal care items, which pose little or no health risks. However, a limited number are classified hazardous substances.
After stimulation, about 20% to 40% of the fluid flows back to the surface and disposed by any one of a number of options. The four most common disposal options are: recycling for additional fracking, treatment and discharge to surface waters, underground injection, and storage in open air pits.
The answer to his question has nothing to do with Pennsylvania’s supposed dismay of the fluid. The answer is matter of simple geology. Pennsylvania’s tightly formed low-porosity underground geology is not suitable for deep injection disposal wells. (1) Correspondingly, Ohio’s geological underbelly composed of deep, cavernous permeable rock formations are ideally suited for injection well holding tanks.(2)
When injection is the most practical solution, the flowback is injected in deep, up to 10,000 feet, underground porous rock formations and sealed above and below by unbroken, impermeable strata. Ohio is home to 176 injection disposal wells, operated by more than 80 companies. Compare that with just six active wells in neighboring Pennsylvania. “There are over 151,000 injection wells around the country injecting over 2 billion gallons of brine every day.(3) Since the 1960s, there have only a handful of incidents due to direct contact or chemical migration into aquifers.”(4)
Both horizontal drilling and hydraulic fracturing are established technologies with a significant track record; horizontal drilling dates back to the 1930s; and hydraulic fracturing has a history actually going back as far as 1860’s, when nitroglycerine was used to stimulate shallow, hard-rock oil reserves, it was surprisingly very successful and not so surprising very hazardous and often illegal.
A key element in the emergence of shale gas exploration has been the refinement of cost‐effective horizontal drilling and hydraulic fracturing technologies. These two processes have allowed shale gas development to move into areas that previously were not accessible, literally your backyard.
The possible harmful effects of the fracking fluid to people and planet cannot be minimized. A 60-year history dictates that hydraulic fracturing is safe. There are few, if any, known cases of anyone being hospitalized or harmed from chemical contact with the fracturing fluid and/or its flowback. Especially, when used in a safe and responsible manner! “Best Management Practices” employed to select sites with the proper geology, construct and cement the casing, and manage the handling, injecting and disposal have just about eliminated problems and complaints.
The dilemma with all this brouhaha over hydraulic fracturing is the lack of concern over:
1. Sodium fluoride found in almost every tube of fluoridated toothpaste, which is far more hazardous and toxic than any of the additives in the hydraulic fracturing fluid.
Sodium fluoride is toxic by ingestion, inhalation and skin contact. “Fluorides are more toxic than lead and only slightly less poisonous than arsenic.”(5) “As of April 7th, 1997, the United States FDA (Food & Drug Administration) has required that all fluoride toothpastes sold in the U.S. carry a poison warning on the label. Another of the little-known facts about fluoride toothpaste is that each tube of toothpaste – even those specifically marketed for children – contains enough fluoride to kill a child.
Fortunately, however, toothpaste-induced fatalities have been rarely reported in the US. In a review of Poison Center Control reports between 1989 and 1994, 12,571 reports were found from people who had ingested excess toothpaste. Of these calls, 2 people – probably both children – experienced “major medical outcomes”, defined as “signs or symptoms that are life-threatening or result in significant residual disability or disfigurement,” see following chart.(6)

2. The environmental impact and water pollution caused by deicing salt. Salt the most commonly used deicing chemical in the United States; it is spread at a rate of approximately 20 million tons per year. “The U.S. Environmental Protection Agency (EPA) does not regulate road salt but acknowledges that special consideration and best management practices are needed to protect reservoirs and other drinking water supplies near treated highways and salt storage sites from contamination with road salt runoff.”(7)
3. The presence of gar gum in natural toothpaste. Guar gum or hydroxyethyl cellulose is one of the hazardous additives used in hydraulic fracturing fluid to thicken the water in the fracturing fluid to suspend the sand. Neither its identity nor concentration is labeled on most tubes of toothpaste.
4. The use of ethylene glycol in many household products, including antifreeze, deicing products, detergents, paints, and cosmetics. Ethylene glycol is a colorless, odorless, sweet-tasting toxic additive used in hydraulic fracturing fluid to prevent scaling in the drill pipe.
“Ethylene glycol that is released into the environment does not persist since it is degraded within days to a few weeks in air, water, and soil. Reports of fatalities following ingestion of ethylene glycol indicate that a volume of 150–1,500 ml consumed at one time may cause death. In humans, the lethal dose of ethylene glycol is estimated to be in the range of 1,400–1,600 mg/kg. Ethylene glycol vapor concentrations measured in the air at airports during de-icing spray operations ranged from 0.05 to 22 mg/m3. Ethylene glycol has also been detected in airport stormwater. Background concentrations of ethylene glycol in the environment are not available.”(8)
5. The dry cleaning of clothes. “You know that smell on clothes that have been to the dry cleaners? Well, for the first time scientists have measured it and found worrying levels of the toxic chemical used most commonly in the dry cleaning process. Most dry cleaners use an oil-based solvent called “Perc” (short for perchloroethylene) that has been linked to serious health problems, particularly for workers or nearby residents who inhale fumes, or for those drinking water contaminated with the chemical. The chemical is such a potent toxic substance that it’s prompted federal and state hazardous waste cleanups at dozens of Superfund sites around the country, some of them at defunct cleaners that didn’t handle their waste properly. And, not surprisingly, the chemical remains on clothes after they come home from the dry cleaners, and even build up over time if clothes are repeatedly dry cleaned, according to a Georgetown University study that was inspired by a sophomore high school student’s science project.”(9)
6. Throwing something away. If you don’t reuse or recycle that item, it probably will end up in a landfill. Once in a landfill the only thing left for it to do is decompose into carbon dioxide, water, hydrogen, ammonia, carbon dioxide, inorganic acids, and methane. “In 2010, Americans generated about 250 million tons of trash and recycled and composted over 85 million tons of this material. On average, we recycled and composted 1.51 pounds out of our individual waste generation of 4.43 pounds per person per day.”(10)
“Decomposition rates (rate at which it will totally break down into the earth) of items in landfills will vary depending on the amount of sunlight, moisture and air exposure it receives. Some of these time ranges are:”(11):
“Apple core: 1 to 2 months, can take longer in landfills due to lack of microbes
Glass bottles: tens of thousands of years; glass is made from sand and it can outlast most anything
Plastic drinking bottles: hundreds of years; consist of polyethylene terephthalate (PET) which is made from petroleum, which won’t break down.
Plastic bags: up to hundreds of years; newer plastic bags can photo-degrade, but most aren’t exposed to sunlight when in a landfill.
Milk carton: 5 years
Plastic milk jug: 500 years
Aluminum can: 80 to 200 years
Styrofoam: no sign of ever breaking down
Cigarette butt: 1 to 5 years
Newspaper: 2 to 4 weeks, can take longer in landfills due to lack of microbes; will decompose much faster when wet.”(11)
7. The December 2008 report that “one in every three of the more than 1,500 children’s toys tested in time for the holiday shopping season have been found to contain “medium” or “high” levels of chemicals of concern such as lead, mercury, cadmium and arsenic.”(12)
In closing, it’s convenient and easy to point at hydraulic fracturing as another human activity that if not curtailed will destroy humanity. The ascent of man is one of risk management and ultimately doing the right thing. Sure controls, oversight and improvements are necessary when our future is at stake. But let’s deal in facts rather than mindless cut and pastes that naysayers righteously proclaim to an unwary public who go about brushing their teeth, driving behind salt spraying trucks, sitting in aircraft during deicing procedures, sending their clothes to the local dry cleaner, buying toys for birthdays and holidays, and shopping to feed and clothe the family without thinking of the potential harm they are doing to themselves and mother earth. Time to put fracking in proper perspective!
References:
(1) “Environmental Impact of the Marcellus Shale,” Energy Facts PA, http://energyfactspa.com/natural-gas/page/environmental-issues
(2) “Fracking Fluid Soaks Ohio,” Bloomberg BusinessWeek, March 22, 2012; http://www.businessweek.com/articles/2012-03-22/fracking-fluid-soaks-ohio
(3) “Class II Wells – Oil and Gas Related Injection Wells (Class II),” U.S. Environmental Protection Agency; http://water.epa.gov/type/groundwater/uic/class2/index.cfm
(4) “Avoid injecting wastewater into faults,” The Marietta Times, March 24, 2012; http://www.mariettatimes.com/page/content.detail/id/543023/Avoid-injecting-wastewater-into-faults.html?nav=5006
(5) “The Dangers of Fluoride,” Global Healing Center; http://www.globalhealingcenter.com/natural-health/how-safe-is-fluoride
(6) “Why is there a Poison Warning on Toothpaste?” Fluoride Action Network; http://www.fluoridealert.org/toothpaste.htm
(7) “Transportation: De-icers Add Sweet to Salt,” Environmental Health Perspectives; http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2592290
(8) “Background and Environmental Exposures to Ethylene Glycol in the United States,” Center for Disease Control; http://www.atsdr.cdc.gov/toxprofiles/tp96-c2.pdf
(9) “Study: Dry Cleaning Chemicals Stick to Clothes,” The Daily Green, http://www.thedailygreen.com/environmental-news/latest/dry-cleaning-chemicals-0911
(10) “Municipal Solid Waste Generation, Recycling, and Disposal in the United States: Facts and Figures for 2010, U.S. Environmental Protection Agency, http://www.epa.gov/osw/nonhaz/municipal/pubs/msw_2010_rev_factsheet.pdf
(11) “Don’t Throw This Away, Landfill Decomposition Rates,” Ways 2 Go Green; http://www.ways2gogreen.com/DontThrowThisAwayDecompositionRates.html
(12) “Toxic Toy Guide Lists Chemicals Found in Hundreds of Toys,” Environment News Service; http://www.ens-newswire.com/ens/dec2008/2008-12-03-01.asp
What’s Your Green IQ?
This is the first for me. Posting an entire article as-is in my blog. Why? A few of the correct answered surprised me. Thought it would be interesting to see how other scored. Answers will appear tomorrow.
This quiz by Colleen Oakley was published in today’s Parade section of the Star-Telegram.
1. On average, how fast do you drive on the highway? (a) 55 mph (b) 65 mph (c) 75 mph
2. When your vehicle needs a bath, do you: (a) Grab the hose and a bucket and do it yourself (b) Go to a car wash
3. What type of driver are you? (a) Aggressive (b) Calm and collected (c) Somewhere in between
4. It’s lunchtime and you’re craving a fast-food burger. Do you: (a) Order at the drive-through (b) Park and head inside to place your order
5. Grilling season is almost here! This summer, you’ll be throwing your burgers and brats onto: (a) An electric grill (b) A charcoal grill (c) A gas grill
6. You’re hosting a cookout and need to stock up on beer. At the store, you fill your cart with: (a) Cans (b) Bottles (c) A keg
7. Okay, you’ve had enough burgers and barbecue. It’s time for a healthy dinner: salmon. At the fish counter, you choose: (a) Atlantic (b) Wild caught from Washington, Oregon, or California (c) Neither; you skip the fish counter and buy canned
8. Now let’s head over to the produce section. With fruits and vegetables, you look for this label: (a) Organic (b) Locally grown (c) I don’t look at labels
9. Your spouse cooked dinner, so you’re on dish duty. Do you: (a) Wash everything by hand (b) Rinse off bits of food, then load the dishwasher (c) Put the dirty dishes straight into the dishwasher
10. After mowing the lawn, what do you do with the clippings? (a) Leave them in the yard (b) Bag them and put them out by the curb
11 When a lightbulb in your house burns out, you replace it with: (a) An incandescent lightbulb (b) A compact fluorescent lightbulb (CFL) (c) A light-emitting diode (LED) bulb
12. You’re cleaning out the medicine cabinet and find a bunch of expired medications. Do you: (a) Flush them down the toilet (b) Toss them in the garbage but recycle the container (c) Return them to the pharmacy
In closing, my score a pitiful 75%; 9 of 12 correct. A “C” at best. How did you do?
Reference:
(1) “How Green Are You,” Colleen Oakley, Parade, Star-Telegram, April 22, 2012 http://www.parade.com/news/2012/04/22-how-green-are-you.html
Need Help – China Content!
I am looking for reliable figures to determine how much content imported from China comprises the installed base of all solar systems in the U.S.
Conditions:
1. Last 5 years
2. In USD
3. Total Cost of all US Solar Systems
4. Total Cost of all components purchased from China
Can anyone assist in finding the answers to these seemingly pragmatic questions?
Feel free to contact me at barry@tbdamericainc.com
Thanks, Barry
GHG on the Rise!
Bottom line! All the brouhaha heard around the world about clean energy hasn’t amounted to a hill of beams.
Why? The 2012 U.S. Greenhouse Gas Inventory Report by the EPA, which summarizes the latest information on U.S. anthropogenic greenhouse gas emission trends from 1990 through 2010 concluded “total U.S. emissions have increased by 10.5 percent from 1990 to 2010. Since 1990, U.S. emissions have increased at an average annual rate of 0.5 percent. Furthermore, “emissions increased from 2009 to 2010 by 3.2 percent.”(1)
The report attributed the increase “from 2009 to 2010 was primarily due to an increase in economic output resulting in an increase in energy consumption across all sectors, and much warmer summer conditions resulting in an increase in electricity demand for air conditioning that was generated primarily by combusting coal and natural gas.”(1)
It’s probably true that without all the strides in wind and solar farms and energy efficiency measures, the trend would be considerably worse. However, it is generally believed within the scientific community that greenhouse gas emissions must be cut in half by 2050 in order to prevent global temperatures from increasing by more than 3.6 degrees Fahrenheit (2 degrees Celsius).
To make matters worse, the U.S. is not alone. In December 2011, The New York Times reported, “Global emissions of carbon dioxide from fossil-fuel burning jumped by the largest amount on record last year, upending the notion that the brief decline during the recession might persist through the recovery. Emissions rose 5.9 percent in 2010…… The increase solidified a trend of ever-rising emissions that scientists fear will make it difficult, if not impossible, to forestall severe climate change in coming decades.”(2)
Even today, The Sidney Morning Herald reported, “Australia’s greenhouse gas emissions continued to rise last year, driven by an increase in vehicle use and gases leaking from coalmines, federal government data show. The nation released 546 million tonnes more carbon dioxide than its land mass absorbed last year, not including the data from changes in land use and logging, which is recorded separately. This is a 0.6 per cent increase on the 2010 emissions figure, still below the nation’s peak in 2008.”(3)
To better understand the trend, this 2002 graph from the EIA presents data on the major global sources of carbon dioxide (CO2) emissions by country, from the beginning of the Industrial Revolution to the present, (4). Only skiers and mountain climbers would enjoy such a profile.
The following world map shows CO2 emissions for 2009 by country.(5) From highest to lowest, the top 10 bad boys for pure CO2 emissions is China, United States, India, Russia, Japan, Germany, Canada, South Korea, Iran and the United Kingdom. There is a large disparity in emissions between China (7,710 metric tonnes) and the UK (520 metric tonnes). A difference of about 1,400%!
The Guardian reported, “on pure emissions alone, the key points are:
- China (#1) emits more CO2 than the US (#2) and Canada (#7) put together – up by 171% since the year 2000
- China generates 23.6 % of global total annual emissions.
- The UK (#10) only produces 1.6 % of global total annual emissions.
- The US has had declining CO2 for two years running, the last time the US had declining CO2 for 3 years running was in the 1980s
- The UK is down one place to tenth on the list, 8% on the year. The country is now behind Iran, South Korea, Japan and Germany
- India is now the world’s third biggest emitter of CO2 – pushing Russia into fourth place
- The biggest decrease from 2008-2009 is Ukraine – down 28%. The biggest increase is the Cook Islands – up 66.7%.”(5)
By per capita emissions, “a different picture emerges where:
- Some of the world’s smallest countries and islands emit the most per person – the highest being Gibraltar with 152 tonnes per person
- The US is still number one in terms of per capita emissions among the big economies – with 18 tonnes emitted per person
- China, by contrast, emits under six tonnes per person, India only 1.38
- For comparison, the whole world emits 4.49 tonnes per person.”(5)
In closing, the trend is obviously going the wrong way. Much more must be done. But what! The 17th Conference of the Parties (“COP17”) to the United Nations Framework Convention on Climate Change (UNFCCC) ended in failure last December. The Kyoto Protocol, which lacked agreement by the U.S. and China, is slated to expire in 2012. What will happen to cap-and-trade, carbon credits and carbon markets in a Post–Kyoto world.?
The real question is – do American’s in the public and private sectors have the resolve, wherewithal and leadership to finally make a difference. Rhetoric says “Yes,” performance says “NO.”
Does it really matter that 2011 tied for the 10th-hottest year since records began in 1850?
Does it really matter that the 13 hottest years on the books all have occurred in the last 15 years?
Does it really matter that Arctic sea ice has also shrunk to record-low volumes?
Does it really matter that “it is estimated that 20 to 30 percent of plant and animal species will be at increased extinction if global temperature rises more than 3.6-5.4 degrees Fahrenheit?(6)
Does it really matter that in the not too distant future humanity may find it difficult to survive on planet earth?
References:
(1) “Inventory of U.S. Greenhouse Gas Emissions and Sinks:,” EPA, April 15, 2012, http://epa.gov/climatechange/emissions/downloads12/US-GHG-Inventory-2012-Main-Text.pdf
(2) “Carbon Emissions Show Biggest Jump Ever Recorded,” The New York Times, December 4, 2011, http://www.nytimes.com/2011/12/05/science/earth/record-jump-in-emissions-in-2010-study-finds.html
(3) “Greenhouse gas emissions still on the rise,” The Sydney Morning Herald, April 18, 2012, http://www.smh.com.au/environment/climate-change/greenhouse-gas-emissions-still-on-the-rise-data-shows-20120417-1x5m4.html
(4) “Global Greenhouse Gas Data,” U.S. Environmental Protection Agency, http://www.epa.gov/climatechange/emissions/globalghg.html
(5) “World carbon dioxide emissions data by country: China speeds ahead of the rest,” The Guardian, January 31, 2011 http://www.guardian.co.uk/news/datablog/2011/jan/31/world-carbon-dioxide-emissions-country-data-co2
(6) “Heat, Livers and Herbivores: Climate change and wildlife,” The Science Times,” Thursday, March 29, 2012 http://thesciencetimes.blogspot.com/2012_03_01_archive.html
Fracking Gets a Fair Shake!
For anyone who thought this piece has to do with hydraulic fracturing or wastewater injection related seismicity, sorry to disappoint. That topic will be covered in a future article. The plan is to post a series of pieces that demystify concerns over; • human health and safety, • the environment, • fresh water reserves, • air quality, and • seismic activity.
To start off, a report by Jazz Shaw, “EPA backs off on fracking contamination claims in Texas” in Hot Air, April 1, 2012, presented recent finding about allegations linking methane contaminated to shale gas production.
Shaw stated:
“….. the EPA has backed out of a lawsuit (involving alleged contamination of ground water by energy exploration efforts) and said that their claims cannot be backed up by the evidence.”
“….. the agency told a federal judge it withdrew an administrative order that alleged Range Resources Corp. had polluted water wells in a rural Texas county west of Fort Worth.”
“….. the EPA sued Range for not complying with its order (to supply water to the affected residents, identify how gas was migrating into the aquifer, stop the flow and clean up the water), Range appealed, arguing that the agency’s analysis was inconclusive. It pointed to nearby water wells that were known to contain high concentrations of gas long before it began drilling.”
“….. it’s also true that you can do that (setting water on fire from natural gas coming up from wells) in homes with in-ground wells all over Pennsylvania and Virginia in places where no drilling has taken place.”
“….. last year that gas most likely seeped into the aquifer from a shallow pocket of gas nearby, not the Barnett Shale, thousands of feet underground, from which Range was producing gas.”
The answers lay in the fact that modern shale gas development is technologically driven and must be treated as such. Unproven cost cutting measures and process deviations are unacceptable. 60 plus years of experience tells us, shale gas can be safely managed and controlled.
In closing, it’s acknowledged that EPA’s change of position, will not detract the greedy, sensationalists and uninformed from its anecdotal attack on the shale gas industry. Our litigacious society supports such actions. Sooner or later the beneficial economic and environmental impact will out way false claims of “fracking fire in the sink. Done right, shale gas production is a low risk proposition.
Fracking Toothpaste
Natural gas production, from hydrocarbon rich shale formations, known as “shale gas,” is one of the most rapidly expanding trends in onshore oil and gas exploration and production today. A key element in the emergence of shale gas exploration has been the refinement of cost‐effective horizontal drilling and hydraulic fracturing technologies.
These two processes, along with the implementation of protective Best Management Practices, have allowed shale gas development to move into areas that previously were not accessible. New gas developments bring change to the ecological and economic landscape. With these changes have come questions about the ability of the technologies to adequately protect the people and the planet. This proposition has taken on almost religious overtones by the media, industry critics and concerned citizens.
Forget for a moment the profound economic impact that shale gas development has on: • creating jobs, • reducing consumer cost of natural gas and electricity, • increasing federal, state and local tax revenue, • stimulating economic growth, and • reducing GHG emissions and smog.
Without exception there were problems with hydraulic fracturing. Modern shale gas development is technologically driven and must be treated as such. Unproven cost cutting measures and process deviations are unacceptable. Investigations into the complaints of water contamination concluded that the problems were avoidable and traced to: • inferior casing and cementing, • insufficient separation between gas-bearing rock and water supplies, and • lack of oversight and adherence to best management practices.
No question, regulations must be imposed to ensure adequate oversight and selection of qualified and trained operators that employ best management practices when handling, injecting and disposing fracturing fluid. Nevertheless, the industry is not standing still. To the rescue are new “green” fracturing additives, better ways to treat and recycle the waste water, and new technologies that reduce water consumption in half.
To put the issue of shale gas development into proper perspective, let’s take a comparative bottom-line look at hydraulic fracturing, oil production and coal mining.
First question is how many people were hospitalized due to methane contaminated water and/or the hydraulic fracturing fluid, a mixture consisting of at least 98% water and sand with the remaining 2%, or less, of chemical additives, each having a specific function. MIT reported there were only 42 complaints of contamination out of 15,000 shale wells drilled in the Texas based Barnett Shale formation – a 0.3% problem.(1) An unofficial posting by “Frack Check WV,” cannot substantiate any hydraulic fracturing related health problems.(2) The posting does mention a few unsubstantiated hydraulic fracturing related severe health claims.
More ludicrous is the human health and safety risks from ethanol. “According to the National Highway Traffic Safety Administration (NHTSA) in 2010 in the United States there were an estimated 10,228 people who died in drunk driving crashes, accounting for 31% of all traffic deaths.(3) Funny yet or maybe not so funny, 70% ethanol may cause liver, kidney and heart damage. Potential health effects include:
• Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
• Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause narcotic effects in high concentration. Vapors may cause dizziness or suffocation.
• Chronic: May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Animal studies have reported the development of tumors. Prolonged exposure may cause liver, kidney, and heart damage.
On the other hand, “Daily Finance”(5) reported that according to Minerals Management Service,
….. “since 2001, 69 oil workers have been killed on the job, with more than 1,300 injuries and around 800 fires.”
….. “the number of oil drilling fatalities doesn’t even come close to the number of coal mining fatalities in America.”
….. “since 2001, there have been more than 60 deaths per year in coal mines, with annual injuries in the tens of thousands.”
Now to the topic of our discussion, everyday household fluoridated toothpaste. It’s suggested that most of us practice and teach our children proper oral hygiene and brush at least one time per day, if not more. The “Fluoride Action Network”(6) reported:
….. “the FDA (Food & Drug Administration) has required that all fluoride toothpastes sold in the U.S. carry a poison warning on the label.”
….. “the label states, “WARNING: Keep out of reach of children under 6 years of age. If you accidentally swallow more than used for brushing, seek professional help or contact a poison control center immediately.”
….. “each tube of toothpaste – even those specifically marketed for children – contains enough fluoride to kill a child.”
….. “Poison Center Control reports between 1989 and 1994, 12,571 reports were found from people who had ingested excess toothpaste. Of these calls, 2 people – probably both children – experienced “major medical outcomes”, defined as “signs or symptoms that are life-threatening or result in significant residual disability or disfigurement.”
One final note, the label of a popular toothpaste states: “Active ingredient – Sodium fluoride 0.243%.” No other ingredients are specified. One would think that it would be somewhat important to know the composition of the remaining 99.757%. Direct searches using for example “toothpaste ingredients” did not provide hits giving the other ingredients. A roundabout search found that some toothpaste may contain: sorbitol, a liquid that keeps toothpaste from drying out, is a laxative that could cause diarrhea in children; and sodium lauryl sulfate, an ingredient that makes toothpaste foam, can also be a diarrheic.
In closing, the witch hunt over hydraulic fracturing can be surmised in one word “HYPOCRISY.” This is another great example of the imbalance of the balance of justice. Every day society holds back the shale gas industry is another day more dollars are exported for foreign oil, the environment is further harmed with dirty coal, and the hole gets deeper and darker.
To the extent that hydraulic fracturing has resulted in few if any substantiated health problems, is a proven technology with a 60 year history, occurs thousands of feet below overlying aquifers and hard non-porous rock, and employs a fluid with publically disclosed chemical additives; alcohol and toothpaste unequivocally pose a much higher risk to human health and safety.
Maybe if the hydraulic fracturing operators take a stiff drink when they report to duty and substitute fluoride for one of the additives, the uniformed critics will lay down their empty wand and finally accept “fracking” as the proper way to achieve good shale gas hygiene?
References:
(1) “The Future of Natural Gas,” MIT Energy Initiative, Interdisciplinary Study, http://web.mit.edu/mitei/research/studies/naturalgas.html
(2) “The Human Story,” Frack Check WV, http://www.frackcheckwv.net/impacts/the-human-story/
(3) The Century Council, “Drunk Driving Fatalities – National Statistics,” http://www.centurycouncil.org/drunk-driving/drunk-driving-fatalities-national-statistics
(4) “Ethyl Alcohol 70%,” Material Data Safety Sheet, http://www.nafaa.org/ethanol.pdf
(5) “Oil and coal worker fatalities aren’t worth limited energy savings,” Daily Finance, http://www.dailyfinance.com/2010/04/30/oil-and-coal-worker-fatalities-arent-worth-limited-energy-savin/
(6) Fluoride Action Network, http://www.fluoridealert.org/toothpaste.htm
Fracking in the Karoo Basin
PetroSA’s Mossel Bay GTL Refinery
Site visit to PetroSA’s GTL Refinery in Mossel Bay, South Africa on 03.23.2012
The visit validated the concern that GTL and thermal waste-to-energy processes are being oversimplified by many claiming to have cost-effective commercial process. From mass and energy balance to metallurgy and complex chemistry, doing it right and being profitable is more demanding than most realize.
PetroSA operates the world’s first and one of the largest Gas to Liquids (GTL) complexes in South Africa Operating since the early 90’s , they have acquired over 16 years of experience through the challenges of commercializing the GTL processes.
The 36 000 bbl/d GTL Refinery, which is based in Mossel Bay, has a crude oil equivalent capacity of 45 000 bbl/day. The principal process is the conversion of natural gas produced offshore to synthetic liquid fuels via the High Temperature Fischer-Tropsch GTL Process. They have led the technology development of Low Temperature Fisher-Tropsch (LTFT) synthesis through their 1,000 bbl/d demonstration plant.
PetroSA’s GTL plant and processes are now well proven, a culture of operational excellence has been firmly embedded and a vision for the future of GTL has been forged. The vision demands that we continually leverage our operational experience to remain at the leading edge of technological innovation in the GTL arena.
Their refinery remains a centre of GTL know-how and operational excellence. It holds the National Occupational Safety Association of South Africa’s (NOSA) five-star grading. It is also further endorsed with SABS/ISO 9002 accreditation, making quality management one of the cornerstones of their operations.
GTL Products
The GTL plant has been producing ultra-clean diesel and naphtha products servicing up to 15 percent of the South African transport fuels market.
The product slate comprises Unleaded gasoline, ultra-low sulphur diesel, kerosene, low aromatic distillates, drilling fluids, liquid petroleum gas, low sulphur fuel oil, anhydrous alcohols, liquid oxygen, liquid nitrogen, carbon dioxide and more recently with the addition of the Low Temperature Fischer Tropsch unit waxes.









